Abstract
AbstractIn Tl2SO2+Na2SO4+di(2‐ethylhexyl)dithiophosphoric acid+n‐C8H18+water system, the Tl+ equilibrium molalities were measured at ionic strength from 0.1 to 2.0 mol·kg‐1 containing Na2SO4 as supporting electrolyte in aqueous phase and at constant molality of extractant at temperatures from 278.15 to 303.15 K in organic phase. The standard extraction constants K0 at various temperatures were obtained by methods of extrapolation and polynomial approximation. Thermodynamic quantities for the extraction process were calculated.
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