Abstract
From the electromotive force (e.m.f.) measurements of cells with liquid-junction potentials, the standard potentials of the silver electrode were obtained in 5%, 10% and 15% (w/w) acetonitrile-water mixtures at five different temperatures ranging from 15 to 35 °C. Standard thermodynamic quantities for the cell reaction were estimated. Thermodynamic solubility product constants of silver halides were computed. The results are discussed in terms of ion solvation.
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