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Abstract
The heat of mixing of liquid argon (component 1) and liquid carbon monoxide has been measured by direct calorimetry for several mixtures of composition ranging from x 1 ⋍ 0.2 to x 1 ⋍ 0.8 at 85.79 K. At this temperature H E is positive and an almost parabolic function of mole fraction, with a maximum value of H E = 95.9 J mol −1 at x 1 = 0.569. The experimental results are compared with those derived from the Gibbons-Rigby equation of state, and from conformal solution theory.
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