Abstract
An adiabatic calorimeter was used to measure the dependence on temperature and composition of the heat capacity C p l(x, T) of liquid magnesium-rich La-Mg-Ni, lanthanum-rich Al-La-Ni alloys and of Al 7.5Cu 17.5Ni 10Zr 65. The C p l(x, T) of these alloys exhibit large values near to the liquidus temperature. C p l(x, T) values of the glass-forming alloys exceed their values of the undercooled liquid state above the glass transition temperature. The C p l dependence on temperature reveals therefore a maximum in the undercooled liquid state. This specific behaviour of liquid alloys is described using an association model.
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