Abstract
A new high-temperature calorimeter was used to study the enthalpies of mixing of nickel-rich Al–Ni melts (mole fraction of Al<0.22) at 1823 K. Concentration dependencies of the partial and integral enthalpies of dissolution of aluminium were obtained experimentally. The model of quasi-ideal associated solutions and ASSOL-2 original software were used to treat and evaluate all available thermodynamic data for liquid Al–Ni system. The description of thermodynamic properties of liquid Al–Ni alloys in a wide concentration and temperature intervals was obtained.
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