Abstract
应用等温流动微量热法测定了298.15K时N,N-二甲基甲酰胺（DMF）在纯水及不同浓度氯化钠水溶液中的稀释焓,根据McMillan-Mayer理论计算得到各级同系焓相互作用系数.结果表明,DMF在纯水及氯化钠水溶液中的焓对相互作用系数h2均为正值,并且随着氯化钠浓度的增加,h2的值逐渐增大.根据溶质-溶质相互作用和溶质-溶剂相互作用对结果进行了解释.
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