Thermodynamics of associated mixtures of the Mecke—Kempter type

Abstract

A chain-forming associated solution theory based on the UNIQUAC equation is presented for alcohol-unassociated active component liquid mixtures of the Mecke—Kempter type. The capability of the theory in reproducing the excess Gibbs free energy and excess enthalpy data for many binary mixtures is successfully shown. Ternary extension of the theory is presented in the calculations of vapor—liquid and liquid—liquid equilibria and excess enthalpy data from binary data.