Abstract

Recent vapor-liquid equilibrium data for four 1-alkanol+n-polyether mixtures are examined on the basis of DISQUAC model -an extension of the surface-interaction version of the quasichemical group contribution theory, to correlate and predict excess enthalpies and excess Gibbs energies for such mixtures at 298.15 K. Using the new data, revised interaction parameters are proposed, which provide a fairly consistent description of the properties of the mixtures as functions of composition.

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