Abstract
Abstract From Brillouin spectra of tetrachloromethane, benzene and cyclohexane measured between 283.15 K and 343.15 K, and carefully re-evaluated data for the heat capacities at constant pressure C P , and constant volume C V , the vibrational contribution to C V was determined and compared with calculated values obtained from the Planck-Einstein relation. Utilizing perfect gas state heat capacity data, the residual heat capacity C V * wa determined and subsequently used to present an estimate for the residual rotational heat capacity (external rotation).
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