Abstract

Thermodynamic study has been made of lithium-vanadium bronzes β-Li x V 2O 5− y in reversible cells with a lithium-conducting solid electrolyte using coulometric titration. The linear dependence of Δ G Li in the bronze on parameters x and T was found. It is concluded that the dependence of Δ G Li on the P O 2 value is weak. The limits of the homogeneity region of β-Li x V 2O 5− y have been more clearly defined.

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