Thermodynamic study of imidazolium halide ionic liquid–water binary systems using excess Gibbs free energy models

Abstract

In this work, the excess Gibbs free energy models, i.e., non-random two-liquid (NRTL) model and electrolyte NRTL model, including the original one and those with new strategies (association or hydration), were used to describe the macroscopic properties and interpret the microstructure of ionic liquid (IL) - H2O binary systems, clarifying the role of IL association and ion hydration in model development. To provide systematic data for model development, the enthalpy of mixing of three imidazolium-based IL-H2O systems containing the same cation but different sizes of anions, i.e., Cl−, Br−, and I−, were measured. The models were developed and evaluated based on the newly measured data and the osmotic coefficient from the literature. The results reveal that the model reflecting the intrinsic mechanism of dissociation and hydration gives the best modeling results; and the ionic strength and the degree of IL dissociation as a function of water content can be predicted using the newly established model. The study clarifies the significance of IL association and anion hydration in model development and quantitatively demonstrates how water content influences the microstructure and real species in IL-H2O systems.