Abstract
In the present work, the stability of gaseous manganese-containing salts was proved by the high-temperature mass spectrometric method. New previously unreported species were found, MnPO3 and MnPO2. On the basis of equilibrium constants measured for gas-phase reactions the standard formation enthalpies for MnPO3 and MnPO2 were determined as −602.0 ± 10.0 kJ/mole and −299.0 ± 11.5 kJ/mole, respectively, and the standard atomization enthalpies as 1950 ± 14 kJ/mole and 1397 ± 14 kJ/mole, respectively.
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