Abstract
The heats of mixing of the DNA-AD, Duplex I-AD and Duplex II-one systems were measured at 298.15 ± 0.005 K by using an LKB batch type twin microcalorimeter with a help of spectral measurements. From the results of DNA-AD system obtained, the interaction between DNA and AD is mainly caused by intercalation manner by referring to the result of spectral measurement. And, we estimated the thermodynamic quantities based on the intercalation process. While, from the results of Duplex I-AD and Duplex II-one systems, we concluded that the interactions of these systems may be corresponded to an electrostatic force as binding process rather than an intercalation process.
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