Abstract
Using arguments derived from classical chemical thermodynamics, it is found that the isobaric, non-isothermal chemical reaction rate is in general a function of heating rate as well as of temperature and composition. However, non-isothermal reaction rate expressions have usually been identified with the corresponding isothermal rate expressions in the literature on non-isothermal chemical reaction kinetics. Generalizing from a specific example, a method is proposed according to which changes in isothermal reaction kinetic expressions may be made to agree with thermodynamics.
Talk to us
Join us for a 30 min session where you can share your feedback and ask us any queries you have
Schedule a callDisclaimer: All third-party content on this website/platform is and will remain the property of their respective owners and is provided on "as is" basis without any warranties, express or implied. Use of third-party content does not indicate any affiliation, sponsorship with or endorsement by them. Any references to third-party content is to identify the corresponding services and shall be considered fair use under The CopyrightLaw.
