Abstract

From e.m.f. measurements carried out with two different solid-electrolyte galvanic cells:Cu|Cu(I) solid ionic conductor|{(1-x-y)Ag+xCu+yS},Ag|Ag(I) solid ionic conductor|{(1-x-y)Ag+xCu+yS},as a function of temperature, ΔfGoms, ΔfHoms, and ΔfSoms of the ternary phase Stromeyerite (Cu1-δAg1-δS) for 0 ⩽ δ ⩽ 0.1 in equilibrium with Cu0.8Ag1.2S, CuS, and Cu1.75S were determined.

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