Abstract

The following thermodynamic properties were determined for 1-pentene, 2-methyl-1-butene, and 2-methyl-2-butane: heats of vaporization at three temperatures, vapor heat capacities at five temperatures, vapor pressures and normal boiling points, second virial coefficients, values of (delta C/sub p//delta P)/sub T/, and the entropies of the vapors at three temperatures. A vibrational assignment was made for 2-methyl-2-butene, and the free energy function, heat content function, entropy and heat capacity of this substance were computed for selected temperatures up to 1500/sup 0/K, by statistical mechanical methods.

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