Abstract
The thermodynamic properties of H2S are calculated from the structure recently obtained by the analysis of an infrared band. — [(F0—E00)/T]*298.1 = 41.174. S*298.1 = 49.151. (Not including the spin contribution.) Montgomery and Kassel's calculations for S2 are corrected in accordance with Badger's new interpretation of the data of Naudé and Christy. — [(F0—E00)/T]298.1 = 47.242. S0298.1 = 54.417. The results are applied to the reaction H2S = H2+½S2. The energy of dissociation of H2S into normal atoms, E00, is found to be 173.8 kg cal. per mole.
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