Abstract
Isometric heat capacity c v and isobaric heat capacity c p of Pt with stable and metastable phases were calculated by using pure element systematic theory. These results are in excellent agreement with of SGTE (Scientific Group Thermodata Europe) database and JANAF (Joint Army-Navy-Air Force) experimental values. The calculation results of c v and c p of Pt metal in natural state are in good agreement with those calculated by FP(first-principles) method. It is found that the electron devotion to heat capacity is important to adjust in OA(one-atom) method while calculating heat capacity. The full information about thermodynamic properties of Pt metal with stable and metastable phases, such as entropy( S), enthalpy( H) and Gibbs energy( G) were calculated from 0 K to random temperature. The results are in good agreement with JANAF experimental value. In contrast to SGTE database, the thermodynamic properties from 0 K to 298.15 K are implemented.
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