Abstract
The potentials for various Pd‐Li alloys in coexisting phase states were investigated in LiCl‐KCl eutectic melt in the temperature range of 673–773 K. The activities and the relative partial molar Gibbs free energies of Li were calculated from the measured potentials for various Pd‐Li alloy phases, i.e., and the liquid phase. The relative partial molar entropies and enthalpies of Li were also calculated for the Pd‐Li alloys by using the temperature dependence of the potentials. Using the Gibbs‐Duhem relation, the activities and the relative partial molar properties of Pd were calculated from the activities of Li for the Pd‐Li alloy phases. Finally, the standard Gibbs free energies of formation were calculated for the Pd‐Li alloy phases.
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