Abstract

AbstractThe partial molar thermodynamic properties of cadmium in molten Cd-Bi-Pb-Sn alloys have been determined using electrochemical concentration cells. The isothermal integral properties were calculated using the analytical method of Pelton. The value of property estimates based on interpolation of empirical series is discussed. Resume Les proprietes thermodynamiques molaires partielles du cadmium dans l'alliage liquide Cd-Bi-Pb-Sn ont ete determinees par voie electrochimique. La methode de Pelton a ete utilisee sur une isotherme pour calculer des proprietes integrales. La validite des estimes de ces proprietes est discutee en se basant sur l'interpolation des series empiriques.

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