Abstract
On liquid Bi—Pb alloys emf measurements were carried out. From the emf data the thermodynamic properties were calculated. In the temperature range between 643 to 923 K no anomalies in the thermodynamic properties were found. The emf varies linearly with temperature and the activity of Pb shows a slight negative deviation fromRaoult's law. However, when ΔH M /x is plotted against (1−x) the results are two staight lines which intersect at approximately 35 at% Bi. This could be interpreted that Bi—Pb melts change from one regular behaviour to another.
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