Abstract
The partial and integral enthalpies of mixing in liquid Al–Si and Al–Cu alloys were determined by high-temperature isoperibolic calorimetry at 1750±5 and 1590±5, respectively. The thermodynamic properties of Al–Si melts were also studied by electromotive force method in temperature range 950–1270 K. The partial and integral excess Gibbs free energies of mixing in liquid Al–Si and Al–Cu alloys were calculated from literature data on thermodynamic activity of aluminium. The comparison of our experimental results with literature data has been performed.
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