Abstract
The literature data on the enthalpies of mixing and thermodynamic activities of Fe–Ti, Fe–Zr, and Fe–Hf liquid alloys are summarized. It is shown that the thermodynamic properties of these systems are characterized by significant negative deviations from the ideal behavior. In the framework of the associated solution model, the composition and temperature dependences of the thermodynamic functions of mixing for the Fe–Ti, Fe–Zr, and Fe–Hf systems are described. The temperature dependence of the thermodynamic properties of the considered systems is characterized by increase in negative deviations from the ideality with decreasing temperature and increasing thermodynamic stability of supercooled melts. Analysis of the degree of short-range order in the system melts, estimated as the total mole fraction of associates Σxass at the glass transition temperature, allows us to successfully interpret the known composition ranges of glass transition for the Fe–Zr and Fe–Hf melts and predict the composition range of glass transition for the Fe–Ti melts.
Talk to us
Join us for a 30 min session where you can share your feedback and ask us any queries you have
Schedule a callDisclaimer: All third-party content on this website/platform is and will remain the property of their respective owners and is provided on "as is" basis without any warranties, express or implied. Use of third-party content does not indicate any affiliation, sponsorship with or endorsement by them. Any references to third-party content is to identify the corresponding services and shall be considered fair use under The CopyrightLaw.
