Abstract

Excess volumes V E and differences in isentropic compressibilities between the solution and the pure state, Δκ s , have been determined at 298.15 K for decalins mixed with hexane isomers. The maximum values of V E are found to correlate linearly with differences of κ s of the pure component liquids. The Δκ s results were used for further detailed discussion of V E. The experimental results are also analysed by using the Flory—Patterson—Prigogine(FPP) theory.

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