Abstract
For the little thermodynamic information of Ta-Sn system, the liquid mixing enthalpy of Ta-Sn system, and the formation enthalpy of Ta2Sn3 and Ta3Sn were calculated by Miedema model. The Ta-Sn phase diagram was modeled using CALPHAD technology to obtain a reliable thermodynamic description of the system. Two intermetallic compounds Ta2Sn and Ta3Sn were treated as stoichiometric compounds for the very narrow homogeneity ranges. The higher temperature phase diagram of Ta-Sn system was constructed according to Nb-Sn system for the empty information. The optimization process was carried out using the PARRAT software including in Thermo-Calc database system. The thermodynamic calculated Ta-Sn phase diagram is agreement with the evaluated phase diagram, and the calculated mixing enthalpies of molten Ta-Sn system match well with the Miedema data. The formation enthalpies of the two intermetallic compounds Ta2Sn and Ta3Sn are compared with the Miedema values.
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