Thermodynamic parameters of adsorption of isomeric chloronaphthalenes on graphitized thermal carbon black

Abstract

Henry's constants and the heats of adsorption of isomeric chloronaphthalenes on graphitized thermal carbon black were calculated by the semiempirical molecular statistical method. The calculated data were compared with experimental results. The best agreement was achieved when corrections for the interaction of the Cl atom with the C atom of the adjacent benzene ring and the presence of other Cl atoms inortho-positions are introduced in calculations of the atom-atomic potential.