Abstract
The thermodynamic model of the extraction of W with primary amine under near neutral conditions is reported in this paper. The activity coefficients of the nonelectrolytes in organic phase are calculated by the Margules and NRTL equations which are based on previously tested liquid-liquid extraction equilibrium data in combination with mass balances and charge balance formula. The activity coefficients of the electrolytes in aqueous phase are calculated by the Pitzer equation. The thermodynamic model of the extraction of W by a primary amine is constructed from the calculated activity coefficients of electrolytes and nonelectrolytes. The extraction of W using primary amine is also predicated, and the data is compared to the calculated results of the thermodynamic model. It is concluded that Margules equation proves to be suitable and reliable for calculating the activity coefficients of nonelectrolytes in complex organic phase systems.
Sign-in/Register to access full text options 
Talk to us
Join us for a 30 min session where you can share your feedback and ask us any queries you have
Schedule a callDisclaimer: All third-party content on this website/platform is and will remain the property of their respective owners and is provided on "as is" basis without any warranties, express or implied. Use of third-party content does not indicate any affiliation, sponsorship with or endorsement by them. Any references to third-party content is to identify the corresponding services and shall be considered fair use under The CopyrightLaw.
