Abstract
ABSTRACTIn this study, a comparative thermodynamic equilibrium calculation of biogas oxy-reforming and oxy-steam reforming processes to produce syngas has been conducted by Aspen Plus simulation software. The effects of temperature (600–800°C), pressure (1−20 atm), and inlet O2/CH4 (0−1.0), H2O/CH4 (0−3.0), and CO2/CH4 (0.3−1.0) mole ratios on the equilibrium compositions of products were determined. The operation of the process was optimized using Gibbs free energy minimization method and statistical approach: response surface methodology (RSM). Optimum operating conditions CH4/CO2/O2 = 1:0.51:0.12 at 788°C and 1 atm for oxy-reforming and CH4/CO2/H2O/O2 = 1:0.63:0.19:0.07 at 780°C and 1 atm for oxy-steam reforming were obtained to reach maximum H2 yield, CH4 and CO2 conversions by minimizing carbon selectivity to produce syngas for methanol production.
Talk to us
Join us for a 30 min session where you can share your feedback and ask us any queries you have
Disclaimer: All third-party content on this website/platform is and will remain the property of their respective owners and is provided on "as is" basis without any warranties, express or implied. Use of third-party content does not indicate any affiliation, sponsorship with or endorsement by them. Any references to third-party content is to identify the corresponding services and shall be considered fair use under The CopyrightLaw.