Abstract

Quasi sub-subregular solution model with additional ternary parameters, used by Sharma et al. to model the thermodynamic properties of the liquid phases in the ternary Al-Ga-Sb, Al-In-Sb, and GaIn-Sb systems, has been extended to predict the thermodynamic properties of the liquid phase in the quaternary Al-Ga-In-Sb system. The (AlGaln)Sb compound phase in the quaternary Al-Ga-In-Sb system is considered a quasi-regular solution of AlSb, GaSb, and InSb compounds. Phase equilibria in the quaternary Al-Ga-In-Sb system are then calculated and compared with the limited experimental data available in the literature. The ternary Al-Ga-In phase diagram, required for the quaternary calculations, has also been modeled and calculated.

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