Abstract
Acidic nickel sulfate solutions are generated in a large scale in the hydro- and pyrometallurgical industries. They are also produced in many industrial processes from nickel refining to surface finishing of metals by electroplating. Acid mine drainage has long been a significant environmental problem in coal and metal mining. The demand of recycling and reuse of materials has increased significantly especially in EU. Dumping a neutralized deposit is not an option any more. Thus, several techniques of recycling and reuse of sulfuric acid and/or metal sulfates from the side streams are needed.When developing alternative solutions, a better understanding of the thermodynamic behavior of NiSO4–H2SO4–H2O system is needed. In this study a thermodynamic model of this system has been developed in order to yield a thermodynamically consistent set of values for the solubility of nickel sulfate in a wide temperature and concentration range. The current model presents the experimental data available with a good accuracy and consistently up to 90°C, and sulfuric acid concentrations up to 10mol/kg. The model also predicts well the solubility measurements available in dilute up to 1.55mol/kg sulfuric acid solutions at 200–250°C.
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