Thermodynamic excess functions of reciprocal silver bromide + alkali chloride melts

Abstract

Excess Gibbs free energies, entropies, and enthalpies of molten silver bromide + alkali chloride (alkali = Na, K, Rb, and Cs) have been measured by use of electrochemical formation cells. The excess Gibbs free energies exhibit a trend similar to that for the simple binary silver bromide + alkali bromide melts, but the deviations from ideality are more positive.