Abstract
The thermodynamic modeling of the Lu–Pb binary system was carried out with the help of CALPHAD (Calculation of PHAse Diagram) method. The liquid phase has been described with the association solution model with “Lu5Pb3” as an associated complex. Lu5Pb3, α-Lu5Pb4, β-Lu5Pb4, Lu6Pb5, and LuPb2 have been treated as stoichiometric compounds, while a sublattice model has been used for the description of the HCP phase. The calculations based on the thermodynamic modeling are in good agreement with the phase diagram data and experimental thermodynamic values.
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