Abstract
Critically assessed data regarding Sn(IV) dioxides and hydroxy complexes have recently been challenged. Differences as large as nine orders of magnitude occur in certain of the published solubility products and other equilibrium constants, despite supposedly being derived from the same ‘reliable’ measurements. We show how these differing conclusions depend on the assignments of uncertainty in the respective experimental observations and that the divergence is due to error propagation in identifiable thermodynamic analyses. The use of Sn4+ as a ‘basis’/‘master’ species in thermodynamic modelling is deprecated. Automatic methods which enable the necessary calculations to be properly evaluated, as well as easily repeated, help uncover such mistakes. The results from the comprehensive NEA review are substantially confirmed.
Talk to us
Join us for a 30 min session where you can share your feedback and ask us any queries you have
Disclaimer: All third-party content on this website/platform is and will remain the property of their respective owners and is provided on "as is" basis without any warranties, express or implied. Use of third-party content does not indicate any affiliation, sponsorship with or endorsement by them. Any references to third-party content is to identify the corresponding services and shall be considered fair use under The CopyrightLaw.