Abstract
Thermodynamic ionization constants over the temperature range 10–60° together with values for the standard free energy, enthalpy and entropy of ionization of m-chlorophenol, m-bromophenol and m-iodophenol are reported. These results in conjunction with an extensive collection of similar results from the literature show that substituent effects in the ionization of phenols are due primarily to entropy changes possibly involving a change of solvation state. In contrast to the free energies of ionization the entropies are well correlated by σ n values.
Sign-in/Register to access full text options 
Talk to us
Join us for a 30 min session where you can share your feedback and ask us any queries you have
Schedule a callDisclaimer: All third-party content on this website/platform is and will remain the property of their respective owners and is provided on "as is" basis without any warranties, express or implied. Use of third-party content does not indicate any affiliation, sponsorship with or endorsement by them. Any references to third-party content is to identify the corresponding services and shall be considered fair use under The CopyrightLaw.
