Thermodynamic consistency of quantum master equations

Abstract

Starting from a microscopic system-baths description, we derive the general conditions for a time-local quantum master equation (QME) to satisfy the first and second law of thermodynamics at the fluctuating level. Using counting statistics, we show that the fluctuating second law can be rephrased as a Generalized Quantum Detailed Balance condition (GQDB), i.e., a symmetry of the time-local generators which ensures the validity of the fluctuation theorem. When requiring in addition a strict system-bath energy conservation, the GQDB reduces to the usual notion of detailed balance which ensures QMEs with Gibbsian steady states. However, if energy conservation is only required on average, QMEs with non Gibbsian steady states can still maintain a certain level of thermodynamic consistency. Applying our theory to commonly used QMEs, we show that the Redfield equation breaks the GQDB, and that some recently derived approximation schemes based on the Redfield equation (which hold beyond the secular approximation and allow to derive a QME of Lindblad form) satisfy the GQDB and the average first law. We find that performing the secular approximation is the only way to ensure the first and second law at the fluctuating level.