Abstract
Thermal dissociation processes for acetonitrile inclusion compounds based on the polymer fluorographite host matrix C2F x Br0.01·yCH3CN, where x = 0.49–0.92, y = 0.174–0.285, are investigated. Thermodynamic parameters (ΔH°av, ΔS°av, ΔG°298) for deintercalation of the compounds of the first filling step into the compounds of the second step and gaseous guest within temperature range 294–352 K were determined. The effect of the host matrix fluorination degree on the thermodynamic characteristics of the studied processes is demonstrated.
Talk to us
Join us for a 30 min session where you can share your feedback and ask us any queries you have
Disclaimer: All third-party content on this website/platform is and will remain the property of their respective owners and is provided on "as is" basis without any warranties, express or implied. Use of third-party content does not indicate any affiliation, sponsorship with or endorsement by them. Any references to third-party content is to identify the corresponding services and shall be considered fair use under The CopyrightLaw.