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Abstract
The pressure-temperature dependence of the vibron stretching mode frequency, the intramolecular bond lengths, and the pressure-volume curves along various isotherms are calculated for fluid ${\mathrm{N}}_{2}$ in the ranges 2\ensuremath{\le}P\ensuremath{\le}150 kbar and 300\ensuremath{\le}T\ensuremath{\le}1500 K. A constant-pressure Monte Carlo procedure with continuously deformable, periodic boundary conditions is used. The results are in good agreement with recent high-temperature diamond cell, dynamic shock, and earlier P-V data.
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