Thermodynamic Calculations and Phase Stabilities in the Y-Si-C-O System

Abstract

A thermodynamic computer dataset for the Y-Si-C-O system was used for calculations of multicomponent, multiphase reactions. The phase reactions of yttrium silicate coatings for the oxidation protection of C/SiC-based composites were analyzed. They were simulated as a function of the temperature and other environmental conditions. To illustrate the high temperature behavior of the coatings, isothermal sections, isopleths, pseudo-binary and -ternary diagrams, phase fraction diagrams, volatility diagrams and potential phase diagrams are presented. Additionally to the thermodynamic aspects, mass balance criteria were taken into account for the analysis of the active/passive oxidation in the coating system.