Thermodynamic behaviour of mixtures containing methyl acetate, methanol, and 1-butanol at 298.15 K: application of the ERAS model

Abstract

Excess molar volumes, and changes of refractive indices, of the ternary mixture methyl acetate+methanol+1-butanol, and the binary mixtures methyl acetate+1-butanol, and methanol+1-butanol have been evaluated from density, and refractive indices measurements at 298.15 K, and 1 atm. These derived properties of binary, and ternary mixtures were fitted to Redlich–Kister, and Cibulka type equations, respectively. The ERAS model interaction parameters of the binary systems contained in the ternary mixture were computed, the obtained results showing good accuracy. The high polar/associative behaviour of the mixtures should be the cause of high deviations in ternary excess prediction. The obtained results suggest the convenience of extending the model to multicomponent polar/associative mixtures in order to take into account all binary polar effects, and higher order polar effects in the mixtures.