Abstract
The integral molar mixing enthalpy of liquid ternary Ga-Sn-Zn alloys has been investigated using drop calorimetry method along five intersections as follows: XGa/XZn = 3/1 at 720 K, xGa/xZn = 1/1 at 718 K and 720 K, xGa/xZn = 1/3 at 718 K, xGa/xSn = 3/17 at 718 K and for xGa/xSn = 1/3 at 720 K. Based on obtained thermodynamic results and those available in the literature the thermodynamic optimization was done using Thermo-Calc software. Next, the phase equilibria in the binary and ternary systems were calculated and the results were compared with those obtained using different experimental techniques.
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