Abstract

The C-Cr-Fe-Ni-O system has recently been studied with the intention to thermodynamically describe the influence of oxygen on high alloyed steels. In this study the ternary Fe-Mn-O system is assessed and part of the binary Mn-O system is reassessed. α- and β-hausmannite (Mn3O4) were earlier described as stoichiometric phases, but are here described using the compound energy formalism with a four sublattice model to be consistent with the preceding study of the Cr-Fe-Ni-O spinel. The liquid phase is assessed using the ionic two-sublattice model. Good agreement between calculated and experimental values is achieved.

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