Abstract

The statistical mechanical equations for the thermophysical properties of dilute gases are evaluated using sophisticated, but still practical potential models with no more than three adjustable parameters. Universal combination rules for these parameters are formulated. It is shown that some data of dilute gas thermophysical properties of monatomic and simple linear molecules yield potential parameters that can be used to predict all other thermophysical properties of the pure gases and their mixtures with excellent accuracy. For monatomic fluids, these potentials are shown to give excellent results of the thermodynamic functions also in the liquid and dense gaseous state.

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