Abstract
The reaction of cis,trans-Fe(CO) 2 (PMe 3 ) 2 MeX with carbon monoxide to give the corresponding cis,trans- and trans,trans-acetyls has been studied in toluene for X Cl>Br>I and are determined by the withdrawing power of X, while the equilibrium constants of trans,trans-acetyl as compared to cis,trans-acetyl follow the order I>Br>Cl>>CN.
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