Thermodynamic and kinetic properties of Ho 1−xTi xCo 2-hydrogen system

Abstract

The hydrogen absorption behavior of Laves phase Ho 1− x Ti x Co 2 ( x=0.1–0.6) alloys has been investigated by pressure-concentration (PC) isotherms and cyclic-, temperature- and pressure-dependent absorption kinetics. The PC isotherms and kinetics of hydrogen absorption have been studied in the pressure range 0.01–1 bar and temperature range 50–200 °C using Sievert's-type apparatus. The drastic changes in the induction period and particle size during the activation process have been discussed based on the kinetics of repeated hydrogenation cycles and scanning electron microscopy (SEM) images of the hydrides at different hydriding cycles, respectively. The experimental results of kinetic curves are interpreted using the Johnson–Mehl–Avrami (JMA) model, and the reaction order and reaction rate have been determined. The α-, ( α+ β)- and β-phase regions in Ho 1− x Ti x Co 2-H have been identified from the different slope regions of the first-order-type kinetic plots. The dependence of the reaction rate parameter on hydriding pressure and temperature in the ( α+ β)-phase region has been discussed.