Abstract

We present analyses of three families of compressed air energy storage (CAES) systems: conventional CAES, in which the heat released during air compression is not stored and natural gas is combusted to provide heat during discharge; adiabatic CAES, in which the compression heat is stored; and CAES in which the compression heat is used to assist water electrolysis for hydrogen storage. The latter two methods involve no fossil fuel combustion. We modeled both a low-temperature and a high-temperature electrolysis process for hydrogen production. Adiabatic CAES (A-CAES) with physical storage of heat is the most efficient option with an exergy efficiency of 69.5% for energy storage. The exergy efficiency of the conventional CAES system is estimated to be 54.3%. Both high-temperature and low-temperature electrolysis CAES systems result in similar exergy efficiencies (35.6% and 34.2%), partly due to low efficiency of the electrolyzer cell. CAES with high-temperature electrolysis has the highest energy storage density (7.9 kWh per m3 of air storage volume), followed by A-CAES (5.2 kWh/m3). Conventional CAES and CAES with low-temperature electrolysis have similar energy densities of 3.1 kWh/m3.

Highlights

  • Large penetrations of wind and solar energies challenge the reliability of the electricity grid, due to their intermittency and uncertainty

  • Our analysis shows that the A-compressed air energy storage (CAES) system has the highest exergy storage efficiency, followed by conventional CAES, and the hydrogen based CAES systems

  • High exergy losses in electrolyzers constitute a key contributor to the overall low storage efficiency of CAES-high temperatures (HTE) and CAES-low-temperature electrolyzer (LTE)

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Summary

Introduction

Large penetrations of wind and solar energies challenge the reliability of the electricity grid, due to their intermittency and uncertainty. CAES stores electrical energy as the exergy of compressed air. Schematic of a generic conventional compressed air energy storage (CAES) system. Harnessing the energy stored in the compressed air Both utilize the temperature increase from the air greenhouse gas (GHG) emissions-free. Utilizing the high-temperature heat of compression the demand electricity hydrogen the high-temperature heat of compression lowers the lowers electricity of demand hydrogenofproduction production in the CAES-HTE system. This paper explores whether the compression heat at sufficiently high temperatures could reduce the electricity demand of hydrogen use of the compression heat at sufficiently high temperatures could reduce the electricity demand of production enough to make the efficiency of CAES-HTE competitive with A-CAES.

Materials and Methods
Modeling Conventional CAES
Schematic
Modeling
Modeling and CAES-LTE
Thermodynamic Comparison of A-CAES and CAES-HTE
Sensitivity of A-CAES and CAES-HTE to Exit Temperature of the HP Compressor
Sensitivity of A-CAES and CAES-HTE to Storage Pressure
Thermodynamics of Conventional CAES and CAES-LTE
Discussion
Thermodynamic Modeling of Conventional CAES
Charge Phase of Conventional CAES
Discharge Phase of Conventional CAES
Roundtrip Analysis of Conventional CAES
Charge Phase of A-CAES
Discharge Phase of A-CAES
Roundtrip Analysis of A-CAES
Charge Phase of CAES-HTE
Findings
Roundtrip Performance of CAES-HTE
Full Text
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