Thermodynamic analysis of a spectrum splitting photovoltaic-thermoelectric system with a multi-physics coupling process

Abstract

Quantifying the losses in the various energy transfer and conversion processes is essential for the study and application of the spectrum splitting photovoltaic-thermoelectric system because of the complex system structure. This paper develops a novel optical-electrical-thermal multi-physics coupling model for the spectrum splitting photovoltaic-thermoelectric system that correlates microstructure and macroscopic properties. Based on the multi-physics coupled model, a thermodynamic analysis method is employed to reveal the distributions of energy and exergy losses in the system, and the effect of the concentration ratio on the losses is investigated. The results show that the optical loss caused by the concentrating and splitting processes accounts for 33.3% of the total input energy. The losses in the energy conversion process are the largest of all the subsystem losses. The energy and exergy losses in the photovoltaic conversion process are 51.5% and 45.9%, while those for the thermoelectric conversion process are 87.8% and 74.5%, respectively. Raising the concentration ratio is an effective way to reduce the exergy loss in the energy conversion process, but it will also partially raise the exergy losses in the heat dissipation and cooling processes. The exergy efficiency of the SSPV-TE system can reach 21.75% at a concentration ratio of 500. The results are important for better understanding the operating principles, optimizing the performance, and advancing the application of the spectrum splitting photovoltaic-thermoelectric system.