Abstract
Uncertainty concerning the magnitudes of key thermodynamic values at the heart of azide chemistry has prevailed for a number of years. The «direct» experimental determination of quantities like Δ f H 0 (N 3 - ,g), differ quite markedly (some 50 kJ mol -1 ) from the values indicated from indirect thermochemical cycles via lattice energies. The viscosity B-coefficients of alkali metal azides in aqueous solution are utilised, in conjunction with a well-established correlation, to estimate these important quantities from a new standpoint
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