Abstract
Calorimetric measurements of the heat of solution of AgBrO3(c) in NH3(aq) have been combined with earlier data on heats of solution of AgNO3(c) in water and in NH3(aq) to yield ΔH0 = 11.78 ± 0.11 kcal mol–1 for AgBrO3(c) = Ag+(aq) + BrO3−(aq). Combination of this value with ΔG0 = 5.83 kcal mol–1 from the solubility product gives ΔS0°= 19.96 cal deg–1 mol–1 for the standard entropy of solution of AgBrO3(c) at 298 °K.
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