Abstract
The heats of the reaction between copper(II) nitrate and sodium alaninate and the heats of dilution of Cu(NO3)2 solution in aqueous ethanol have been measured at 298 K using calorimetry. The standard molar enthalpies of the reaction of copper(II) complexing with alaninate ion in solvents of various compositions have been calculated. The complexing process in ethanol is more exothermic than that in water. The role of solvation effects in the thermodynamics of formation of amino acid complexes has been discussed.
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