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Abstract
The standard molar enthalpies of formation of crystalline dialkyldithiocarbamate chelates of mercury(II) were determined by using reaction-solution calorimetry. Two different complexes were studied: Hg(S2CNR2)2 with R = CH3 (Me) and i-C3H7 (Pri). The enthalpies of formation for the mercury complexes were determined in 1,2-dichloroethane at 298 K. The hemolytic and heterolytic mean enthalpies of dissociation of the Hg–S bonds were calculated by using the standard molar enthalpy of the gaseous chelates.
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